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Beilstein J. Org. Chem. 2015, 11, 524–529, doi:10.3762/bjoc.11.59
Graphical Abstract
Figure 1: Pharmaceutically active 2- and 2,3-disubstituted morpholines.
Scheme 1: One-pot synthesis of morpholines through ring opening of aziridines with haloalcohols.
Scheme 2: Metal-free one-pot synthesis of morpholine 3a from aziridine 1a.
Scheme 3: Metal-free one-pot synthesis of optically pure morpholine derivatives from chiral aziridines.
Scheme 4: Proposed mechanism.